- Department of Civil Engineering
University of Beira Interior
6201-001 Covilhã, Portugal - +351 965 103 990
- João Castro-Gomes is full Professor at the Department of Civil Engineering and Architecture of University of Beira In... moreJoão Castro-Gomes is full Professor at the Department of Civil Engineering and Architecture of University of Beira Interior and was scientific coordinator of C-MADE, Centre of Materials and Building Technologies R&D unit between 2007 and 2014 (https://cmadeubi.wordpress.com), having been responsible for its foundation.
He concluded his PhD in mathematical models for assessing cement hydration and microstructure of cement pastes, in 1997 at University of Leeds (UK) and joined afterwards the Department of Civil Engineering at University of Beira Interior (PT). Since then he was been particularly involved in the installation of different research laboratories in the field of materials and construction technology, namely the laboratory of durability of materials. He also was responsible for the implementation of the first Master Course in the Department of Civil Engineering (http://www.mreamb.ubi.pt/planoestudos.htm), for the implementation of the Erasmus program and for the establishment of first Doctoral Program of studies in Civil Engineering. In his scientific activity, has been responsible for developing several research projects submitted for National and European funding, some of then involving SMEs and industry.
Regarding PhD supervision, he has supervised 6 PhD students and co-supervised 2 PhD students, is now supervising 2 PhD theses. He is also permanently involved in training on laboratory-based research initiation of final year students and graduates.
Castro-Gomes current research interests are: Environmentally sustainable binders and composites (low-CO2 binders, alkali activated/geopolymeric cements, CO2 activated cements, reuse of industrial and household wastes, particularly mining waste, polymer composites incorporating wastes); Technologies for sustainable construction (minimization of raw materials, energy-efficiency buildings, recycling of building materials, vegetated surfaces modular systems); and Microstructure of Materials (scanning electron microscopy analysis, X-ray diffraction, laser diffraction, thermogravimetric analysis, infrared spectroscopy and mercury micro porosimetry); tests indicating parameters of durability: permeability to gases and water, carbonation and chloride diffusion, porosity and capillary absorption, action of water and freeze-thaw action; Service life models).edit
This review discusses the potential of alkali-activated materials obtained from mineral waste. A brief historical background on alkali-activated materials is presented. Recent advances in the development of binders obtained from mineral... more
This review discusses the potential of alkali-activated materials obtained from mineral waste. A brief historical background on alkali-activated materials is presented. Recent advances in the development of binders obtained from mineral wastes and alkali-activated solutions are described. The scope of this state of the art review is to identify current knowledge in support that mineral waste can be used for the production of alkali-activated binders. In addition, this review identifies the chemical activators that can be effectively utilized for such purposes in the age when wastes are still viewed by industry as disposable. Some mineral wastes which are discussed can be viewed as a new resource for recycling and recovery which will offer important economic and social benefits.
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Panasqueira is one of the oldest underground mines in Portugal. The mine has been active for over 125 years. Panasqueira contains one of the largest economic viable tungsten vein deposits in the world. The tungsten is the main product of... more
Panasqueira is one of the oldest underground mines in Portugal. The mine has been active for over 125 years. Panasqueira contains one of the largest economic viable tungsten vein deposits in the world. The tungsten is the main product of exploitation of Panasqueira. The mine is today operated by Sojitz Beralt Tin & Wolfram (Portugal) SA. The ore deposits consist of a series of stacked, sub-horizontal, hydrothermal quartz veins that lead into mineralized wolfram-bearing schists and shales (Cavey & Gunning, 2006). The min-eralized zone has dimensions of approximately 2,500 m in length, varying in width from 400 m to 2,200 m, and continues to at least 500 m in depth. Wolframite, cassiterite and chalcopyrite are the extracted minerals obtained. Such minerals are treated to make concentrates of tungsten, tin and copper, respectively. The current extraction methodology is a mechanized room-and-pillar method, based on an analysis of geological and geomechanical characteristics of the rock mass. The ore treatment process begins with heavy media separation for the coarse fractions of material. It enables removing about 80% of the ore that has no tungsten content. Afterwards, this pre-concentrated material is subjected to a conventional gravity concentration method, followed by sulphide removal using flotation and final dry magnetic separation (Franco et al., 2014). Until 1996, the pre-concentrates were transported to the Rio plant, but today, the final separation procedures are carried out exclusively in the Barroca Grande plant. A huge tailings pile and two mud dams now exist at this site. One of the dams is still being fed with material with-ABSTRACT: Based on the initial results obtained in the research program REMINE (H2020 RISE-Marie Curie Action) in progress, authors discuss the potential use of Panasqueira mine waste aggregates and fillers in the production of construction materials for transportation infra-structures. An estimate of the economic and social impact that this form of recycling could have on the local communities and on the perspective of other mining activities in Portugal and Eu-rope is given. The main goals of the project are to explore materials design methods of alkali-activated composites from mining/quarrying wastes based on the demanding requirement of rheology to fit for various processing techniques and applications. The development of artificial aggregates through alkali-activation of mining waste presents itself as a viable technical solution to compete with other commonly adopted materials and may lead to the manufacturing of less porous and harder aggregates for the production of most of the road paving materials.
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To ensure the durability of concrete structures it is necessary to understand its behaviour in the presence of aggressive agents. Carbonation and chloride action are the two leading causes of degradation in reinforced concrete structures.... more
To ensure the durability of concrete structures it is necessary to understand its behaviour in the presence of aggressive agents. Carbonation and chloride action are the two leading causes of degradation in reinforced concrete structures. Despite the combined action of these two mechanisms being a reality, there is little research on the effect of CO2 presence on the chloride behaviour in concrete. This work studies the total chlorides ingress into carbonated concrete. For this, samples with CEM I 42.5R were cast with 0.6 of water/binder ratio. After 90 days of the curing period, half of the samples were subjected to accelerated carbonation (20ºC, 55%Relative Humidity and 4%CO2) for 1 month. The other half was protected with a plastic film during the same period. Chloride immersion test, based on LNEC E390 (Portuguese specification), were performed with samples subjected to both experimental conditions. Afterwards, the depth of chlorides and CO2 penetration was evaluated. The results show that, for these conditions, the CO2 presence has a direct influence on chloride behaviour. The non-carbonated samples showed a profile with a higher amount of chloride than carbonated ones.
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Tungsten mining waste (TMT) has accumulated in the billions of tonnes in the mines of Western Europe, which is problematic because reuse options for this material are limited. TMT is inherently an aluminosilicate and therefore possesses... more
Tungsten mining waste (TMT) has accumulated in the billions of tonnes in the mines of Western Europe, which is problematic because reuse options for this material are limited. TMT is inherently an aluminosilicate and therefore possesses the capacity to be used as a suitable raw material for the production of alkali activated binders (AAB) that exhibit high strength, rapid setting, good durability and high resistance to chemical attack. This research presents the results of preparation conditions optimized for the production of an AAB using TMT and waste glass (WG). It is demonstrated that the problematic mining waste can be successfully transformed into a suitable AAB when moisture loss is prevented and activator preparation parameters such as mixing and rest time are precisely controlled.
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Green walls can protect building envelope from surrounding environment while contributing to improve buildings design and thermal performance. The design concept of a new modular system (Geogreen) for vegetated surfaces has been developed... more
Green walls can protect building envelope from surrounding environment while contributing to improve buildings design and thermal performance. The design concept of a new modular system (Geogreen) for vegetated surfaces has been developed to create more sustainable green roofs and green walls. This paper aims to present the study of Geogreen system thermal performance in a Mediterranean climate. This work is based on the evaluation of local meteorological conditions in three different periods. The Geogreen system is tested in an exterior test cell, comprising a reference wall and a wall covered with Geogreen modules. The analysis is based in the interior surface temperatures and interior surface heat fluxes of two compartments with the same dimensions and thermal characteristics. Resuts show that Geogreen system contributes to: reduce maximum interior surface temperatures and increase minimum interior surface temperatures up to 7 °C; mitigate heat transfer, reducing maximum income heat flux by 75% and maximum outgoing heat flux by 60%; enhance thermal insulation of a wall; and increase thermal delay between the exterior and the interior. These aspects can lead to reduce and shift airconditioning power loads and to improve buildings thermal performance.
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Due to communication and technology developments, residential consumers are enabled to participate in Demand Response Programs (DRPs), control their consumption and decrease their cost by using Household Energy Management (HEM) systems.... more
Due to communication and technology developments, residential consumers are enabled to participate in Demand Response Programs (DRPs), control their consumption and decrease their cost by using Household Energy Management (HEM) systems. On the other hand, capability of energy storage systems to improve the energy efficiency causes that employing Phase Change Materials (PCM) as thermal storage systems to be widely addressed in the building applications. In this paper, an operational model of HEM system considering the incorporation of more than one type of PCM in plastering mortars (hybrid PCM) is proposed not only to minimize the customer’s cost in different DRPs but also to guaranty the habitants’ satisfaction. Moreover, the proposed model ensures the technical and economic limits of batteries and electrical appliances. Different case studies indicate that implementation of hybrid PCM in the buildings can meaningfully affect the operational pattern of HEM systems in different DRPs. The results reveal that the customer’s electricity cost can be reduced up to 48% by utilizing the proposed model.
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This paper analyses the possibility of using altered aggregates and Reclaimed Asphalt Pavement (RAP) in cold mix asphalt used to produce grouted macadam pavements in comparison with the conventional hot mix porous asphalt skeleton. It... more
This paper analyses the possibility of using altered aggregates and Reclaimed Asphalt Pavement (RAP) in cold mix asphalt used to produce grouted macadam pavements in comparison with the conventional hot mix porous asphalt skeleton. It also nvestigates the cementitious grouts performance when incorporated with milled glass and Panasqueira Waste Mud and geopolymerics grouts. This paper aims mainly at studying the introduction of mineral waste materials in grouted macadam pavements. The results indicate that the cold mixture 8/12.5 with altered granite and cementitious grout with 30% milled glass presents the best mechanical performance.
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Current systems for greening the buildings envelope are not just surfaces covered with vegetation. Greening systems, as green roofs and green walls, are frequently used as an aesthetical feature in buildings. However, the current... more
Current systems for greening the buildings envelope are not just surfaces covered with vegetation. Greening systems, as green roofs and green walls, are frequently used as an aesthetical feature in buildings. However, the current technology involved in these systems can maximize the functional benefits of plants to buildings performance and make part of a sustainable strategy of urban rehabilitation and buildings retrofitting. During the last decades several researches were conducted proving that green walls can contribute to enhance and restore the urban environment and improve buildings performance. The aim of this paper is to review all types of green wall systems in order to identify and systematize their main characteristics and technologies involved. So, it is important to understand the main differences between systems in terms of composition and construction methods. Most recent developments in green walls are mainly focused in systems design in order to achieve more efficient technical solutions and a better performance in all building phases. Yet, green wall systems must evolve to become more sustainable solutions. In fact, continuing to evaluate the contribution of recent green wall systems to improve buildings performance and comparing the environmental impact of these systems with other construction solutions can lead to an increase of their application in buildings and therefore result in a reduction on these systems cost. The decision of which green wall system is more appropriate to a certain project must depend not only on the construction and climatic restrictions but also on the environmental impact of its components and associated costs during its entire lifecycle.
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Research and practical experience have shown that partial replacement of cement by metakaolin improves concrete durability as a result of the refinement of the pore structure. While much research has been presented on concrete performance... more
Research and practical experience have shown that partial replacement of cement by metakaolin improves concrete durability as a result of the refinement of the pore structure. While much research has been presented on concrete performance with metakaolin, it is scarce concerning the transport properties of chlorides in concrete with metakaolin, in natural conditions (i.e., un-accelerated). This study determines the chloride diffusion coefficients for several concretes with vary levels of cement replacement with metakaolin, and compares these results with chloride migration coefficients obtained from accelerated laboratory testing. In this study, two
cement types (CEM I 42,5R and CEM IV/A 42,5) and two cement contents levels where used with metakaolin replacement levels
varying from 10-20%. Concretes where tested for fresh properties, compressive strength, electrical resistivity, chloride ingress characteristics (natural diffusion and migration), and mercury intrusion porosimetry. The results show improved strength, durability properties and chloride penetration resistance of concretes with metakaolin. Furthermore, the use of metakaolin in fly ash concrete improves the early age performance of the concrete (<90 days), counteracting the delay in strength and durability gain typically associated with fly ash concrete. The results obtained from this study fulfil the lack of critical input for service life design models of reinforced concrete structures in chloride environments, with emphasis on concretes with metakaolin replacement.
cement types (CEM I 42,5R and CEM IV/A 42,5) and two cement contents levels where used with metakaolin replacement levels
varying from 10-20%. Concretes where tested for fresh properties, compressive strength, electrical resistivity, chloride ingress characteristics (natural diffusion and migration), and mercury intrusion porosimetry. The results show improved strength, durability properties and chloride penetration resistance of concretes with metakaolin. Furthermore, the use of metakaolin in fly ash concrete improves the early age performance of the concrete (<90 days), counteracting the delay in strength and durability gain typically associated with fly ash concrete. The results obtained from this study fulfil the lack of critical input for service life design models of reinforced concrete structures in chloride environments, with emphasis on concretes with metakaolin replacement.
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Se presentan nuevos materiales cerámicos obtenidos a partir de residuos de minería de tungsteno que son extraídos en la región de Beira Interior en Portugal, con nulo aprovechamiento comercial a la par que provocan graves problemas... more
Se presentan nuevos materiales cerámicos obtenidos a partir de residuos de minería de tungsteno que son extraídos en la
región de Beira Interior en Portugal, con nulo aprovechamiento comercial a la par que provocan graves problemas paisajísticos
y medioambientales. Los nuevos productos cerámicos, preparados en un amplio rango térmico (desde 800 ºC a 1300 ºC) han
sido evaluados mediante ensayos mecánicos principalmente, aunque también han sido caracterizadas las materias primas de
partida: restos de minería de tungsteno y caolín industrial, con los que han sido conformados. Los resultados, que incluyen
también una caracterización mineralógica de los productos cerámicos y evaluación morfológica de neoformados mediante
microscopía electrónica de barrido, ponen de manifiesto, en primer lugar, la factibilidad de transformar un gran número de
estos residuos en productos cerámicos comercializables. Gracias a la experimentación realizada, se puede obtener una pasta
industrial con 90 % de residuo sin modificar dramáticamente sus propiedades. Así se pueden generar materiales cerámicos
prácticamente sin la presencia de minerales de la arcilla, dada la particular composición de estos residuos de minería con
presencia de óxidos ácidos, neutros y básicos.
región de Beira Interior en Portugal, con nulo aprovechamiento comercial a la par que provocan graves problemas paisajísticos
y medioambientales. Los nuevos productos cerámicos, preparados en un amplio rango térmico (desde 800 ºC a 1300 ºC) han
sido evaluados mediante ensayos mecánicos principalmente, aunque también han sido caracterizadas las materias primas de
partida: restos de minería de tungsteno y caolín industrial, con los que han sido conformados. Los resultados, que incluyen
también una caracterización mineralógica de los productos cerámicos y evaluación morfológica de neoformados mediante
microscopía electrónica de barrido, ponen de manifiesto, en primer lugar, la factibilidad de transformar un gran número de
estos residuos en productos cerámicos comercializables. Gracias a la experimentación realizada, se puede obtener una pasta
industrial con 90 % de residuo sin modificar dramáticamente sus propiedades. Así se pueden generar materiales cerámicos
prácticamente sin la presencia de minerales de la arcilla, dada la particular composición de estos residuos de minería con
presencia de óxidos ácidos, neutros y básicos.
Research Interests:
This article addresses to the issue of durability related properties of self-compacting concrete (SCC) with the use of coarse recycled aggregates obtained from demolition of concrete structures. The objective was to verify the influence... more
This article addresses to the issue of durability related properties of self-compacting concrete (SCC) with
the use of coarse recycled aggregates obtained from demolition of concrete structures. The objective was
to verify the influence of recycled aggregates on SCC permeability properties. For this purpose four
different types of concrete mixes were produced, one of them used as reference with natural coarse
aggregates and the others prepared with 20%, 40% and 100% of recycled coarse aggregates. The properties related to the durability of SCC, as air and water permeability and capillary absorption were determined on concrete specimens with and without preconditioning. The results from fresh and hardened concrete
properties lead to the conclusion that it is viable to replace natural coarse aggregates by recycled coarse aggregates since the present research does not show any detrimental to the SCC permeability properties.
the use of coarse recycled aggregates obtained from demolition of concrete structures. The objective was
to verify the influence of recycled aggregates on SCC permeability properties. For this purpose four
different types of concrete mixes were produced, one of them used as reference with natural coarse
aggregates and the others prepared with 20%, 40% and 100% of recycled coarse aggregates. The properties related to the durability of SCC, as air and water permeability and capillary absorption were determined on concrete specimens with and without preconditioning. The results from fresh and hardened concrete
properties lead to the conclusion that it is viable to replace natural coarse aggregates by recycled coarse aggregates since the present research does not show any detrimental to the SCC permeability properties.
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The objective of this study is to evaluate the use of polyurethane (PU) coated textile wastes processed with ethylene-vinyl acetate (EVA) as lightweight aggregates in fly ash-based and alkali-activated metakaolin mortars, targeting the... more
The objective of this study is to evaluate the use of polyurethane (PU) coated textile wastes processed with ethylene-vinyl acetate (EVA) as lightweight aggregates in fly ash-based and alkali-activated metakaolin mortars, targeting the development of non-structural elements for civil construction. The PU/EVA waste was processed in three different proportions: 30/70, 50/50 and 70/30. Reference mortars were prepared using a 1:2 (fly ash + metakaolin: conventional construction sand) ratio, by mass. The PU/EVA-waste-containing mortars were prepared via partial replacement of natural sand with the waste in percentages of 10%, 20%, 30% and 40%, relative to the volume of the sand. The activators used in all mortars were NaOH and Na2SiO3. The mortars were cured at 80 °C for 21 hours and subsequently removed from the molds and maintained at room temperature until testing was conducted for compressive strength (at ages of 7, 28 and 91 days), leaching (7 days) and solubilization (7 days). Based on the results for compressive strength, the optimum PU/EVA content was 50% for a sand-to-waste replacement percentage of 40%. At an age of 28 days these mortars reached strengths greater than 2.5 MPa which, from a mechanical standpoint, allows for the production of non-structural elements for civil construction like sealing blocks, side walls or finish mortars. From an environmental perspective, no hazardous substances were detected in the leaching and solubilized extracts in any of the PU/EVA waste containing mortars.
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The objective of this study is to evaluate the effect of the relationship of waste polyurethane (PU) and Ethylene-Vinyl Acetate (EVA), as a replacement for conventional construction sand, on the physical properties of water absorption,... more
The objective of this study is to evaluate the effect of the relationship of waste polyurethane (PU) and Ethylene-Vinyl Acetate (EVA), as a replacement for conventional construction sand, on the physical properties of water absorption, bulk density and open porosity of fly ash-based and alkali-activated metakaolin mortars. By means of processing involving extrusion and milling, PU/EVA-based aggregates were prepared in three proportions: 30/70, 50/50 and 70/30. The reference alkali-activated mortars were prepared using a 1:2 (fly ash + metakaolin : conventional construction sand) ratio, by weight. The waste-containing mortars were prepared via partial replacement of construction sand with the PU/EVA waste in percentages of 10%, 20%, 30% and 40%, relative to the volume of sand. The activators used in all mortars were NaOH and Na2SiO3. The mortars were cured at 80oC for 21 hours. Based on the procedures of ASTM C 642, the water absorption, open porosity and bulk density of the alkali-activated mortars were determined at the ages of 7, 28 and 91 days. The open porosity and water absorption values increased as the amount of sand replaced with PU/EVA waste increased. The absorption values were found to be in the range from 8.0% to 17.00%. The values obtained for open porosity varied from 20.00% to 29.00%. With regard to bulk density, the behavior was reversed: increasing the amount of sand replaced by waste, decreased the bulk density value. The values ranged between 2.10 and 2.48 kg/dm3. Therefore, based on these results, mortars containing up to 40% PU/EVA have potential for use in the manufacture of non-load-bearing elements for civil construction.
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Nas minas da Panasqueira (Covilhã, Portugal) acumulam-se montes de resíduos (agregados) provenientes da extração de tungsténio sem qualquer aplicação. Este trabalho pretende contribuir para implementar um novo uso para estes resíduos... more
Nas minas da Panasqueira (Covilhã, Portugal) acumulam-se montes de resíduos (agregados) provenientes da extração de
tungsténio sem qualquer aplicação. Este trabalho pretende contribuir para implementar um novo uso para estes resíduos
integrando-os como revestimento refratário no processo de moldação a verde da fundição de metais não ferrosos. Os resultados mostram o potencial do uso destes resíduos da fundição de metais não ferrosos.
tungsténio sem qualquer aplicação. Este trabalho pretende contribuir para implementar um novo uso para estes resíduos
integrando-os como revestimento refratário no processo de moldação a verde da fundição de metais não ferrosos. Os resultados mostram o potencial do uso destes resíduos da fundição de metais não ferrosos.
Research Interests:
Extensive research and practical experience have shown that partial replacement of cement by metakaolin improves concrete durability as a result of the refinement of the pore structure. While literature confirms much research on the... more
Extensive research and practical experience have shown that partial replacement of cement by metakaolin improves concrete durability as a result of the refinement of the pore structure. While literature confirms much research on the performance of concrete with metakaolin, it is scarce concerning the performance with regards to chloride penetration, and the effect on the service life of reinforced concrete structures. In this study, several concrete mixes were cast with varying cement type and content and were evaluated for their chloride penetration performance. Reference mixes where made with CEM I 42,5R and CEM IV/A 42,5 type cements. Two cement contents levels where defined: 330 kg/m 3 and 440 kg/m 3 based on mix designs currently used in the ready-mix industry for C20/25 and C30/37 concretes. Cement was replaced with metakaolin with levels varying from 10-20%. All concretes where tested for fresh properties, compressive strength, electrical resistivity and chloride diffusion characteristics (migration and ponding), and mercury intrusion porosimetry. The results demonstrate the improved resistance to chloride penetration of concretes with metakaolin additions. A beneficial effect on strength and durability properties of metakaolin was also observed. In addition, service life design calculations of reinforced concrete structures in marine environment based on the performance indicators obtained show a significant increase in the time to fulfil the serviceability limit state of corrosion initiation.
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Rural houses are usually built with traditional materials, stone and wood, and have a poor thermal and hygrometric behaviour. On the other hand, this kind of residences are generally degraded, and it is necessary to study adequate... more
Rural houses are usually built with traditional materials, stone and wood, and have a poor thermal and hygrometric behaviour. On the other hand, this kind of residences are generally degraded, and it is necessary to study adequate solutions to rehabilitate roofing (wood structures), walls (stone masonry) and floors (wood), particularly to improve house envelop resistance to water penetration and thermal comfort. Is it also urgent, as well, to study and develop adequate methodologies for the rehabilitation of such typical construction having this specific characteristics. Thus, under this scope, an experimental study on hygrothermal behaviour of retrofit solutions applied to old building stone masonry walls is presented. This analysis has been carried out in order to evaluate the influence of some wall retrofit solutions that can increase its thermal resistance. The study took place in laboratory, using a climate chamber, in which variations of temperature and humidity that occur in a stone masonry wall have been measured. The results obtained in laboratory were compared with analytical results obtained using specific software for the assessment of probability of occurrence of walls internal condensation. The experimental results obtained in this work contribute to a better understanding of the thermal-hygrometric behaviour of stone masonry walls, when thermal rehabilitation solutions are applied to its inside surface. The study also points out the importance of using repair-building solutions that can minimize the risk of superficial and internal condensation.
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s habitações rurais são, em geral, constituídas com materiais tradicionais, pedra e madeira, e apresentam um fraco comportamento térmico e higrométrico. Por outro lado, este tipo de habita- ção encontra-se em geral degradado, tornando- se... more
s habitações rurais são, em geral, constituídas com materiais tradicionais, pedra e madeira, e apresentam um fraco comportamento térmico e higrométrico. Por outro lado, este tipo de habita- ção encontra-se em geral degradado, tornando- se necessário estudar soluções para reabilitar coberturas (estruturas de madeira), paredes (alvenaria de pedra) e pavimentos (madeira), melhorando a sua impermeabilização e conforto térmico, bem como, estudar metodologias ade- quadas para a reabilitação de construções com as características indicadas. Neste artigo foi efectuado um estudo experimental para avaliar a influência de algumas soluções construtivas, no aumento da resistência térmica de paredes de alvenaria de pedra. O estudo decorreu em câ- mara climática, no qual se mediram as variações de temperatura e humidade que ocorrem numa parede de alvenaria de pedra, para algumas das soluções testadas previamente com o software Condensa. Os resultados experimentais obtidos neste trabalho, contribuem para um maior co- nhecimento do comportamento termo-higromé- trico de paredes de alvenaria de pedra, quando a reabilitação térmica é feita pelo seu interior e utilizando soluções construtivas que minimi- zam os riscos de condensação superficial.
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The durability of concrete is intrinsically related to the properties of the cement paste present in a concrete element. Properties such as permeability and diffusion depend on the microstructural characteristics of hydrated cement. These... more
The durability of concrete is intrinsically related to the properties of the cement paste present in a concrete element. Properties such as permeability and diffusion depend on the microstructural characteristics of hydrated cement. These characteristics are influenced by the mixing and curing conditions, particularly the w/c ratio, the curing temperature and the relative humidity, and the degree of hydration. The study of cement microstructural parameters such as total porosity, pore size distribution and nature and amount of hydrated products as well as the engineering properties such as permeability, absorption and diffusion have been the main concern of researchers who intended to improve the durability of concrete. The current literature indicates that new experimental techniques and methods have been developed for the characterisation of the cement microstructure. This research presents a study of the characterisation of hydrated cement. The hydrated cement products and porosity of the pastes are quantified with the object of developing quantitative models to predict the degree of hydration with relation to the age of the cement paste. These predictive models will form the basis for predicting properties related to the performance and durability of concrete. The hydrated cement products were quantified with backscattered imaging and the degree of hydration was obtained from this study. A new method to calculate the degree of hydration using backscattered imaging is proposed. The degree of hydration obtained with backscattered imaging is comparable to the degree of hydration obtained with traditional techniques such as thermogravimetric analysis and specific gravity measurements. A model to predict the degree of hydration was developed in this research work. This model uses modified conceptual equations based on the classical theory of nucleation and diffusion growth which have been used to describe the development of compressive strength. Finally, the cement microstructure was characterised using the theory of Fractals. The morphology of the different products of hydration observed in cement microstructure was associated with a single number. This number is called the fractal dimension. These fractal dimensions were found to be statistcally correlated with the degree of hydration and thus could be used as characteristic parameters.
